NOTE: It is recommended that the A/C system be serviced by an EPA Section 609 certified automotive technician utilizing a refrigerant recovery/recycling machine.
The do-it-yourselfer should not service his/her own vehicle's A/C system for many reasons, including legal concerns, personal injury, environmental damage and cost.
According to the U.S. Clean Air Act, it is a federal crime to service or repair (involving the refrigerant) a Motor Vehicle Air Conditioning (MVAC) system for money without being EPA certified. It is also illegal to vent R-12 refrigerant into the atmosphere. State and/or local laws may be more strict than the federal regulations, so be sure to check with your state and/or local authorities for further information.
NOTE: Federal law dictates that a fine of up to $25,000 may be levied on people convicted of venting refrigerant into the atmosphere.
When servicing an A/C system you run the risk of handling or coming in contact with refrigerant, which may result in skin or eye irritation or frostbite. Although low in toxicity (due to chemical stability), inhalation of concentrated refrigerant fumes is dangerous and can result in death; cases of fatal cardiac arrhythmia have been reported in people accidentally subjected to high levels of refrigerant. Some early symptoms include loss of concentration and drowsiness.
Also, some refrigerants can decompose at high temperatures (near gas heaters or open flame), which may result in hydrofluoric acid, hydrochloric acid and phosgene (a fatal nerve gas).
It is usually more economically feasible to have a certified MVAC automotive technician perform A/C system service on your vehicle.